(S)-(-)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二噁茂

(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (订货以英文为准)

编号:S138469
CAS号:210169-54-3
分子式:C38H28O4P2
分子量:610.57
货号 品牌 包装 目录价 您的价格 库存 数量 购买
S138469-250mg 阿拉丁 250mg ¥265.90
S138469-1g 阿拉丁 1g ¥576.90
S138469-25g 阿拉丁 25g ¥3553.90
S138469-5g 阿拉丁 5g ¥813.90
产品名称 (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole
中文名称 (S)-(-)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二噁茂
CAS号 210169-54-3
MDL编码 MFCD09753005
分子式(M.F.) C38H28O4P2
分子量(M.W.) 610.57
储存条件 充氩
敏感性对湿度敏感,对空气敏感
存贮条件充氩保存
应用Chiral biaryl bisphosphine catalytic ligand used for:· Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes· Stereoselective preparation of homoallylic alcohols via Ir-catalyzed stereoselective transfer hydrogenative crotylation of an allylic acetate with alcohols or aldehydes· Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives· Diastereo- and enantioselective hydrogenation of α-amino-β-keto ester hydrochlorides catalyzed by an iridium complex· Preparation of dihydroisoquinolinones via nickel-catalyzed denitrogenative annulation of benzotriazinones with 1,3-dienes and alkenes· Stereoselective preparation of indanol derivatives via Rh-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes
别名(S)-(-)-4,4'-双(二苯基膦)-3,3'-二(1,2-亚甲基二氧苯);(S)-(-)-SEGPHOS (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (S)-(-)-4,4'-Bis(diphenylphosphino)-3,3'-bi(1,2-methylenedioxybenzene)
WGK德国3
闪点(摄氏)108 °C
搜索质检报告(COA)
搜索MSDS
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