敏感性 | 对湿度敏感,对空气敏感 |
存贮条件 | 充氩保存 |
应用 | Chiral biaryl bisphosphine catalytic ligand used for:· Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes· Stereoselective preparation of homoallylic alcohols via Ir-catalyzed stereoselective transfer hydrogenative crotylation of an allylic acetate with alcohols or aldehydes· Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives· Diastereo- and enantioselective hydrogenation of α-amino-β-keto ester hydrochlorides catalyzed by an iridium complex· Preparation of dihydroisoquinolinones via nickel-catalyzed denitrogenative annulation of benzotriazinones with 1,3-dienes and alkenes· Stereoselective preparation of indanol derivatives via Rh-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes |
别名 | (S)-(-)-4,4'-双(二苯基膦)-3,3'-二(1,2-亚甲基二氧苯);(S)-(-)-SEGPHOS (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (S)-(-)-4,4'-Bis(diphenylphosphino)-3,3'-bi(1,2-methylenedioxybenzene) |
(S)-(-)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二噁茂
(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (订货以英文为准)
编号:S138469
CAS号:210169-54-3
分子式:C38H28O4P2
分子量:610.57
产品名称 | (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole |
中文名称 | (S)-(-)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二噁茂 |
CAS号 | 210169-54-3 |
MDL编码 | MFCD09753005 |
分子式(M.F.) | C38H28O4P2 |
分子量(M.W.) | 610.57 |
储存条件 | 充氩 |
WGK德国 | 3 |
闪点(摄氏) | 108 °C |
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