熔点 | 160-165°C |
应用 | Catalyst for:1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones2Highly selective rhodium-catalyzed hydrogenation reactions3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes.Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes.Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis. |
别名 | ;Tri-3,5-xylylphosphine |
三(3,5-二甲苯基)膦
Tris(3,5-dimethylphenyl)phosphine (订货以英文为准)
编号:T123980
CAS号:69227-47-0
分子式:C24H27P
分子量:346.44
产品名称 | Tris(3,5-dimethylphenyl)phosphine |
中文名称 | 三(3,5-二甲苯基)膦 |
CAS号 | 69227-47-0 |
MDL编码 | MFCD03094579 |
分子式(M.F.) | C24H27P |
分子量(M.W.) | 346.44 |
标识符号 | https://www.aladdin-e.com/images/ghs/ghs02.jpg,https://www.aladdin-e.com/images/ghs/ghs05.jpg |
信号词 | Danger |
危害声明 | H250,H314 |
警示性声明 | P222,P231,P280,P305+P351+P338,P310,P422 |
个人防护设备 | Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter |
WGK德国 | 3 |
闪点(摄氏) | 210 °C |
风险声明 (欧洲) | 17,34 |
安全声明(欧洲) | 26,36/37/39,45 |
危害码(欧洲) | F,C |
UN代码 | 2845 |
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