4-乙氧基-1,1,1-三氟-3-丁烯-2-酮

4-Ethoxy-1,1,1-trifluoro-3-buten-2-one (订货以英文为准)

编号:W132795
CAS号:17129-06-5
分子式:C2H5OCH=CHCOCF3
分子量:168.11
货号 品牌 包装 目录价 您的价格 库存 数量 购买
W132795-1g 阿拉丁 1g ¥29.90
W132795-5g 阿拉丁 5g ¥47.90
W132795-25g 阿拉丁 25g ¥190.90
W132795-100g 阿拉丁 100g ¥1326.90
产品名称 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
中文名称 4-乙氧基-1,1,1-三氟-3-丁烯-2-酮
CAS号 17129-06-5
MDL编码 MFCD00192131
分子式(M.F.) C2H5OCH=CHCOCF3
分子量(M.W.) 168.11
储存条件 2-8°C储存;充氩
沸点48°C/11mmHg
折光率n20/D 1.406
敏感性对湿度敏感
存贮条件储存温度2-8°C,充氩保存
密度1.1800
应用4-Ethoxy-1,1,1-trifluoro-3-buten-2-one may be used in the synthesis of 4-dialkylamino-1,1,1-trifluorobut-3-ene-2-ones. It may be used for the synthesis of β-alkyl- or dialkylamino substituted enones bearing a CF3 group.
产品介绍4-Ethoxy-1,1,1-trifluoro-3-buten-2-one reacts with phenylmagnesium bromide to afford ethoxy group substitution products, while it reacts with organozinc compounds to yield products arising from 1,2-addition to the carbonyl group. 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one on heating with triethyl phosphite affords [4+2] cycloaddition product, 2,2,2-triethoxy 2,3-dihydro-3-ethoxy-5-trifluoromethyl-1,2λ5-oxaphospholene, which on hydrolysis affords a 2-oxo-2-hydroxy-2, 3-dihydro-3-hydroxy 5-trifluoromethyl-1,2λ5-oxaphospholen.It reacts with amino to give the N-protected amino acids, which is useful for the peptide synthesis.
别名(E)-4-乙氧基-1,1,1-三氟-3-丁烯-2-酮;(E)-4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
搜索质检报告(COA)
搜索MSDS
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