沸点 | 116-117 °C |
折光率 | 1.451 |
敏感性 | 对湿度敏感 |
溶解性 | Sparingly soluble in water (0.043 g/L at 25°C). |
存贮条件 | 充氩保存 |
密度 | 0.7510 |
应用 | (tert-Butyldimethylsilyl)acetylene may be used in the synthesis of β-alkynylketone[1] and β-alkynyl aldehydes. |
产品介绍 | (tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.(tert-Butyldimethylsilyl)acetylene readily undergoes cross-dimerization reaction with various internal phenyl acetylenes in the presence of rhodium dimers and bidentate phosphine ligands to afford enynes. |
别名 | 叔丁基乙炔基二甲基硅烷;叔丁基二甲基硅烷乙炔;(tert-Butyl)ethynyldimethylsilane;tert-Butyldimethylsilylacetylene |
(叔丁基二甲基硅烷基)乙炔
(tert-Butyldimethylsilyl)acetylene (订货以英文为准)
编号:T162479
CAS号:86318-61-8
分子式:C8H16SI
分子量:140.30
产品名称 | (tert-Butyldimethylsilyl)acetylene |
中文名称 | (叔丁基二甲基硅烷基)乙炔 |
CAS号 | 86318-61-8 |
分子式(M.F.) | C8H16SI |
分子量(M.W.) | 140.30 |
储存条件 | 充氩 |
Reaxys-RN | 1071222 |
信号词 | Danger |
危害声明 | H225-H302-H311-H314 |
警示性声明 | P210-P280-P305 + P351 + P338-P310 |
个人防护设备 | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
WGK德国 | 3 |
闪点(摄氏) | -7°C |
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